Dibromidobis[1-(2-bromobenzyl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
Dibromidobis[1-(2-bromobenzyl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
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In the title complex, [CuBr2(C14H11BrN4O)2], the CuII ion is located on an inversion centre and is coordinated here by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment.The two carbonyl groups are trans positioned with C=O bond lengths of 1.256 (5) Å, in agreement with a classical carbonyl bond.The Cu—O bond length is 2.011 (3) Å.
The two bromobenzyl rings are approximately parallel to one another, forming a dihedral angle of 70.1 (4)° with la rams crop top the coordination plane.